Fortschritte in der angewandten Wissenschaftsforschung Offener Zugang

Abstrakt

FTIR studies of hydrogen bonding interaction between the hydroxyl and carbonyl liquids

P. Krishnamurthi P., Ramalingam H. B. and Raju K.

The intermolecular hydrogen bonding interaction between p-chlorophenol and amyl acetate has been investigated by FT-IR spectroscopy. This article mainly reports the results of p-chlorophenol with carbon tetrachloride solution and in the presence of amyl acetate. The spectroscopic characteristics of OH….O complexes are specified. Also, the formation constant for 1:1 and 1:2 complexes at 25o C were evaluated by the methods of Nash, Whetsel-Kagaraise and Becker. The free energy of 1:1 and 1:2 complexes were obtained from the formation constant values. The formation constant and free energy values indicate that existence of 1:1 and 1:2 complexes